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- W2624539266 abstract "The reaction of carbon nucleophiles with acyl azolium intermediates to form ketones is challenging. In their Communication on page 7402 ff., A. Studer et al. demonstrate an efficient strategy for the synthesis of optically active spiroindolenines with an α-all-carbon quaternary stereocenter through intramolecular dearomatizing C3-acylation of indoles by using oxidative carbene catalysis. The spiroindolenines are obtained in excellent yields and with excellent enantioselectivity. The reaction of carbon nucleophiles with acyl azolium intermediates to form ketones is challenging. In their Communication on page 7402 ff., A. Studer et al. demonstrate an efficient strategy for the synthesis of optically active spiroindolenines with an α-all-carbon quaternary stereocenter through intramolecular dearomatizing C3-acylation of indoles by using oxidative carbene catalysis. The spiroindolenines are obtained in excellent yields and with excellent enantioselectivity. Plant Fertilizer Ester Hydrogenation B−O Bond Cleavage" @default.
- W2624539266 created "2017-06-15" @default.
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- W2624539266 date "2017-05-31" @default.
- W2624539266 modified "2023-10-16" @default.
- W2624539266 title "Cover Picture: Oxidative N-Heterocyclic Carbene Catalyzed Dearomatization of Indoles to Spirocyclic Indolenines with a Quaternary Carbon Stereocenter (Angew. Chem. Int. Ed. 26/2017)" @default.
- W2624539266 doi "https://doi.org/10.1002/anie.201704766" @default.
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