Matches in SemOpenAlex for { <https://semopenalex.org/work/W2624890242> ?p ?o ?g. }
Showing items 1 to 86 of
86
with 100 items per page.
- W2624890242 abstract "Kinetics of hexacyanoferrate (III) (HCF) oxidation of fluorene (Fl) in organic alkaline medium has been studied by spectrophotometric technique at a constant ionic strength of 0.15 mol dm-3 and at a temperature of 25°C. The reaction showed a first order kinetics with respect to [HCF] and fractional-first order dependences on both [Fl] and [OH-]. The oxidation rate was increased with the increase in the ionic strength of the reaction medium. The oxidation mechanism was suggested which involves formation of a 1:1 intermediate complex between fluorene and HCF species in a pre-equilibrium step. The final oxidation product of fluorene was identified by spectroscopic and chemical tools as 9H-fluorenone. The appropriate rate law expression was deduced and the reaction constants involved in the mechanism were evaluated. The activation parameters of the rate constant of the slow step along with the thermodynamic quantities of the equilibrium constants were evaluated and discussed." @default.
- W2624890242 created "2017-06-23" @default.
- W2624890242 creator A5047258036 @default.
- W2624890242 date "2017-01-01" @default.
- W2624890242 modified "2023-09-25" @default.
- W2624890242 title "A Study of the Kinetics and Mechanism of Oxidation of Fluorene by Alkaline Hexacyanoferrate(III)" @default.
- W2624890242 doi "https://doi.org/10.11648/j.ajpc.20170603.12" @default.
- W2624890242 hasPublicationYear "2017" @default.
- W2624890242 type Work @default.
- W2624890242 sameAs 2624890242 @default.
- W2624890242 citedByCount "1" @default.
- W2624890242 countsByYear W26248902422019 @default.
- W2624890242 crossrefType "journal-article" @default.
- W2624890242 hasAuthorship W2624890242A5047258036 @default.
- W2624890242 hasBestOaLocation W26248902421 @default.
- W2624890242 hasConcept C10710636 @default.
- W2624890242 hasConcept C111163200 @default.
- W2624890242 hasConcept C121332964 @default.
- W2624890242 hasConcept C145148216 @default.
- W2624890242 hasConcept C147789679 @default.
- W2624890242 hasConcept C148898269 @default.
- W2624890242 hasConcept C161790260 @default.
- W2624890242 hasConcept C175113610 @default.
- W2624890242 hasConcept C178790620 @default.
- W2624890242 hasConcept C179104552 @default.
- W2624890242 hasConcept C184651966 @default.
- W2624890242 hasConcept C185592680 @default.
- W2624890242 hasConcept C187428577 @default.
- W2624890242 hasConcept C2182769 @default.
- W2624890242 hasConcept C2776211377 @default.
- W2624890242 hasConcept C2777768854 @default.
- W2624890242 hasConcept C36663273 @default.
- W2624890242 hasConcept C521977710 @default.
- W2624890242 hasConcept C62520636 @default.
- W2624890242 hasConcept C65024703 @default.
- W2624890242 hasConcept C75473681 @default.
- W2624890242 hasConcept C93391505 @default.
- W2624890242 hasConceptScore W2624890242C10710636 @default.
- W2624890242 hasConceptScore W2624890242C111163200 @default.
- W2624890242 hasConceptScore W2624890242C121332964 @default.
- W2624890242 hasConceptScore W2624890242C145148216 @default.
- W2624890242 hasConceptScore W2624890242C147789679 @default.
- W2624890242 hasConceptScore W2624890242C148898269 @default.
- W2624890242 hasConceptScore W2624890242C161790260 @default.
- W2624890242 hasConceptScore W2624890242C175113610 @default.
- W2624890242 hasConceptScore W2624890242C178790620 @default.
- W2624890242 hasConceptScore W2624890242C179104552 @default.
- W2624890242 hasConceptScore W2624890242C184651966 @default.
- W2624890242 hasConceptScore W2624890242C185592680 @default.
- W2624890242 hasConceptScore W2624890242C187428577 @default.
- W2624890242 hasConceptScore W2624890242C2182769 @default.
- W2624890242 hasConceptScore W2624890242C2776211377 @default.
- W2624890242 hasConceptScore W2624890242C2777768854 @default.
- W2624890242 hasConceptScore W2624890242C36663273 @default.
- W2624890242 hasConceptScore W2624890242C521977710 @default.
- W2624890242 hasConceptScore W2624890242C62520636 @default.
- W2624890242 hasConceptScore W2624890242C65024703 @default.
- W2624890242 hasConceptScore W2624890242C75473681 @default.
- W2624890242 hasConceptScore W2624890242C93391505 @default.
- W2624890242 hasLocation W26248902421 @default.
- W2624890242 hasOpenAccess W2624890242 @default.
- W2624890242 hasPrimaryLocation W26248902421 @default.
- W2624890242 hasRelatedWork W1972446879 @default.
- W2624890242 hasRelatedWork W2003970635 @default.
- W2624890242 hasRelatedWork W2017437576 @default.
- W2624890242 hasRelatedWork W202387357 @default.
- W2624890242 hasRelatedWork W2077814569 @default.
- W2624890242 hasRelatedWork W2187418396 @default.
- W2624890242 hasRelatedWork W2227340328 @default.
- W2624890242 hasRelatedWork W2274526292 @default.
- W2624890242 hasRelatedWork W2279042119 @default.
- W2624890242 hasRelatedWork W2299436511 @default.
- W2624890242 hasRelatedWork W2308770878 @default.
- W2624890242 hasRelatedWork W2318422017 @default.
- W2624890242 hasRelatedWork W2460215919 @default.
- W2624890242 hasRelatedWork W2560783842 @default.
- W2624890242 hasRelatedWork W3120423188 @default.
- W2624890242 hasRelatedWork W3188152372 @default.
- W2624890242 hasRelatedWork W2182869144 @default.
- W2624890242 hasRelatedWork W2183214124 @default.
- W2624890242 hasRelatedWork W2183462891 @default.
- W2624890242 hasRelatedWork W2462660835 @default.
- W2624890242 isParatext "false" @default.
- W2624890242 isRetracted "false" @default.
- W2624890242 magId "2624890242" @default.
- W2624890242 workType "article" @default.