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• W2624954994 abstract "A series of para‐toluene sulfonamide ligands [TsNHPr‐i( HL 1 ), TsNHBu‐t( HL 2 ), TsNHPh( HL 3 ), TsNHPhMe‐p( HL 4 ), TsNHPhOMe‐p( HL 5 )] were synthesized by amidation using para‐toluene sulfonyl chloride reacting with different primary amines. A series of homoleptic lanthanide complexes (Ln L 3 , 1–10) (Ln = La, L = L 1 ( 1 ), Ln = Gd, L = L 2 ( 2 ), Ln = La, L = L 2 ( 3 ), Ln = Gd, L = L 2 ( 4 ), Ln = La, L = L 3 ( 5 ), Ln = Gd, L = L 3 ( 6 ), Ln = La, L = L 4 ( 7 ), Ln = Gd, L = L 4 ( 8 ), Ln = La, L = L 5 ( 9 ), Ln = Gd, L = L 5 ( 10 )) were prepared by amine elimination reactions of the ligands with Ln[N(SiMe 3 ) 2 ] 3 (Ln = La, Gd). Complexes 1 , 3 , 5 , 7 and 9 were all characterized by NMR spectra, and the structures of complex 3 was determined by single‐crystal X‐ray diffraction. Complex 3 crystallizes a binuclear cluster, consisting of two La 3+ and six (TsNBu‐t) − anions. Three (TsNBu‐t) − anions are chelating to each La 3+ as bidentate model with O and N forming three‐membered chelate rings; one of three anions is bridging to another La 3+ via oxygen. All complexes were characterized using elemental analysis and infrared spectra. The catalytic properties of complexes 1–10 for the ring‐opening polymerization of ε‐caprolactone were studied and the results showed that all complexes are efficient initiators for this ring‐opening polymerization reaction." @default.
• W2624954994 created "2017-06-23" @default.
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• W2624954994 date "2017-06-19" @default.
• W2624954994 modified "2023-10-09" @default.
• W2624954994 title "Synthesis and structure of para-toluene sulfonamide lanthanide complexes and their application in the polymerization of ε-caprolactone" @default.
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• W2624954994 doi "https://doi.org/10.1002/aoc.3828" @default.
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