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- W2625539897 abstract "Abstract 1,4‐Dioxepines result from the decomposition of α‐diazo‐β‐keto esters in the presence of oxetanes using the catalytic combination of the (cyclopentadienyl)ruthenium complex [CpRu(CH 3 CN) 3 ][BAr F ] and 1,10‐phenanthroline. The regioselective [4+3] insertions follow an S N 1‐like mechanism and occur yet enantiospecifically ( es 74%). The retention of configuration was ascertained by vibrational circular dichroism (VCD) and solid state analyses. Furans, products of [4+1] insertions, are only observed as traces in the above protocol. To promote their formation under CpRu catalysis, it is necessary to use a two‐step process with γ‐halogenated alcohols as substrates. magnified image" @default.
- W2625539897 created "2017-06-23" @default.
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- W2625539897 date "2017-08-16" @default.
- W2625539897 modified "2023-10-16" @default.
- W2625539897 title "Regioselective and Enantiospecific Synthesis of Dioxepines by (Cyclopentadienyl)ruthenium-Catalyzed Condensations of Diazocarbonyls and Oxetanes" @default.
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- W2625539897 doi "https://doi.org/10.1002/adsc.201700638" @default.
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