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- W2625624603 abstract "General quadratic Hamiltonian models, describing interaction between crystal molecules (typically with $D_{2h}$ symmetry) take into account couplings between their uniaxial and biaxial tensors. While the attractive contributions arising from interactions between similar tensors of the participating molecules provide for eventual condensation of the respective orders at suitably low temperatures, the role of cross-coupling between unlike tensors is not fully appreciated. Our recent study with an advanced Monte Carlo technique (entropic sampling) showed clearly the increasing relevance of this cross term in determining the phase diagram, contravening in some regions of model parameter space, the predictions of mean field theory and standard Monte Carlo simulation results. In this context, we investigated the phase diagrams and the nature of the phases therein, on two trajectories in the parameter space: one is a line in the interior region of biaxial stability believed to be representative of the real systems, and the second is the extensively investigated parabolic path resulting from the London dispersion approximation. In both the cases, we find the destabilizing effect of increased cross-coupling interactions, which invariably result in the formation of local biaxial organizations inhomogeneously distributed. This manifests as a small, but unmistakable, contribution of biaxial order in the uniaxial phase.The free energy profiles computed in the present study as a function of the two dominant order parameters indicate complex landscapes, reflecting the difficulties in the ready realization of the biaxial phase in the laboratory." @default.
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- W2625624603 date "2017-09-22" @default.
- W2625624603 modified "2023-09-24" @default.
- W2625624603 title "Complex free-energy landscapes in biaxial nematic liquid crystals and the role of repulsive interactions: A Wang-Landau study" @default.
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- W2625624603 doi "https://doi.org/10.1103/physreve.96.032703" @default.
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