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• W2625627124 abstract "Abstract Three new mixed valence trinuclear Co(II/III) compounds [Co3L2(μ2-C6H5CO2−)2(CH3CN)2](ClO4−)2·(CH3CN)3 (1) [Co3LR2(μ2-C6H5CO2−)2(C6H5CO2−)2]·(CH3CN)2 (2) and [Co3LR2(μ2-C6H5CH CH CO2−)2(C6H5CH CH CO2−)2]·((CH3)2CO)2 (3) have been synthesized by reacting the di-Schiff base ligand [H2L] or its reduced analog [H2LR] (where H2L = N,N′-bis(salicylidene)-1,3-propanediamine) and (H2LR = N,N′-bis(2-hydroxybenzyl)-1,3-propanediamine) with cobalt perchlorate hexahydrate and sodium benzoate or sodium cinnamate. The complexes have been characterized by IR, UV–Vis and single crystal X-ray diffraction analyses. All the complexes are linear trinuclear species [CoIII CoII CoIII] in which two terminal octahedral CoIIIN2O2 cores coordinate to the central octahedral CoII ion through μ2-phenoxido oxygen atom and the bridging carboxylato ions. In addition, the complexes (2 and 3) derived from reduced Schiff base ligand have, rather unusually, a terminally coordinated carboxylato ion to CoIII, which is acetonitrile molecule in case of complex (1) with unreduced ligand. Complex 2 has been found to be an excellent functional model for the phenoxazinone synthase activity, in the aerial oxidation of 2-aminophenol to the corresponding 2-aminophenoxazine-3-one chromophore in acetonitrile solvent medium. Detailed kinetic data analysis of this oxidation reaction reveals a fairly high phenoxazinone synthase activity of 2 with kcat = 153.60 h−1." @default.
• W2625627124 created "2017-06-23" @default.
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• W2625627124 date "2017-09-01" @default.
• W2625627124 modified "2023-09-24" @default.
• W2625627124 title "Mixed valence trinuclear cobalt (II/III) complexes: Synthesis, structural characterization and phenoxazinone synthase activity" @default.
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• W2625627124 doi "https://doi.org/10.1016/j.poly.2017.06.007" @default.
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