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• W2625654375 abstract "Abstract Liquid crystal, while being a core component in liquid crystal displays, also has potential harmful effects on ecosystems and human health, especially when it is not treated properly. In this study, a hydrothermal process is proposed to dispose liquid crystal of 1-ethyl-4-[(4-methoxyphenyl)ethynyl]benzene (EMOPE) and mixed liquid crystal of EMOPE and 4-octoxy-4′-cyanobiphenyl (OCBPh). The effect of reaction time, reaction temperature, oxidant addition and solid-to-liquid ratio on decomposition ratio is evaluated. Products from hydrothermal decomposition of EMOPE are characterized, and two possible hydrothermal decomposition pathways are proposed. To get complete decomposition of 4 mg of EMOPE, the conditions required are: 0.3 mL of H 2 O 2 addition, 3.5 mL of water supply, 275 °C and 5 min. The decomposition kinetic analysis of EMOPE indicates that its decomposition process fits the apparent first-order reaction model. For the mixture’s decomposition, given conditions of 275 °C, reaction time of 6 min, 3.5 mL of water supply, and 1.5 time of oxidant addition, the decomposition ratio of OCBPh reaches to 99.75%, and EMOPE can be completely decomposed." @default.
• W2625654375 created "2017-06-23" @default.
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• W2625654375 date "2017-10-01" @default.
• W2625654375 modified "2023-09-27" @default.
• W2625654375 title "The decomposition process and kinetic analysis of benzene-based liquid crystal in hydrothermal system" @default.
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• W2625654375 doi "https://doi.org/10.1016/j.cej.2017.06.065" @default.
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