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- W2626362425 abstract "Abstract Soluble platinum nanoparticles (Pt NPs) ligated by two different long‐chain N‐heterocyclic carbenes (LC‐IPr and LC‐IMe) were synthesized and fully characterized by TEM, high‐resolution TEM, wide‐angle X‐ray scattering (WAXS), X‐ray photoelectron spectroscopy (XPS), and solution NMR. The surface chemistry of these NPs (Pt@LC‐IPr and Pt@LC‐IMe) was investigated by FT‐IR and solid state NMR using CO as a probe molecule. A clear influence of the bulkiness of the N‐substituents on the size, surface state, and catalytic activity of these Pt NPs was observed. While Pt@LC‐IMe showed no activity in the hydroboration of phenylacetylene, Pt@LC‐IPr revealed good selectivity for the trans ‐isomer, which may be supported by a homogeneous species. This is the first example of hydroboration of acetylenes catalyzed by non‐supported Pt NPs." @default.
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- W2626362425 date "2017-07-26" @default.
- W2626362425 modified "2023-10-15" @default.
- W2626362425 title "Soluble Platinum Nanoparticles Ligated by Long‐Chain N‐Heterocyclic Carbenes as Catalysts" @default.
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- W2626362425 doi "https://doi.org/10.1002/chem.201702288" @default.
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