FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2626388906> ?p ?o ?g. }

• W2626388906 endingPage "234501" @default.
• W2626388906 startingPage "234501" @default.
• W2626388906 abstract "Many of water’s remarkable properties arise from its tendency to form an intricate and robust hydrogen bond network. Understanding the dynamics that govern this network is fundamental to elucidating the behavior of pure water and water in biological and physical systems. In ultrafast nonlinear infrared experiments, the accessible time scales are limited by water’s rapid vibrational relaxation (1.8 ps for dilute HOD in H2O), precluding interrogation of slow hydrogen bond evolution in non-bulk systems. Here, hydrogen bonding dynamics in bulk D2O were studied from the perspective of the much longer lived (36.2 ps) CN stretch mode of selenocyanate (SeCN−) using polarization selective pump-probe (PSPP) experiments, two-dimensional infrared (2D IR) vibrational echo spectroscopy, and molecular dynamics simulations. The simulations make use of the empirical frequency mapping approach, applied to SeCN− for the first time. The PSPP experiments and simulations show that the orientational correlation function decays via fast (2.0 ps) restricted angular diffusion (wobbling-in-a-cone) and complete orientational diffusive randomization (4.5 ps). Spectral diffusion, quantified in terms of the frequency-frequency correlation function, occurs on two time scales. The initial 0.6 ps time scale is attributed to small length and angle fluctuations of the hydrogen bonds between water and SeCN−. The second 1.4 ps measured time scale, identical to that for HOD in bulk D2O, reports on the collective reorganization of the water hydrogen bond network around the anion. The experiments and simulations provide details of the anion-water hydrogen bonding and demonstrate that SeCN− is a reliable vibrational probe of the ultrafast spectroscopy of water." @default.
• W2626388906 created "2017-06-23" @default.
• W2626388906 creator A5029192239 @default.
• W2626388906 creator A5050040176 @default.
• W2626388906 creator A5078149381 @default.
• W2626388906 date "2017-06-21" @default.
• W2626388906 modified "2023-10-18" @default.
• W2626388906 title "Water-anion hydrogen bonding dynamics: Ultrafast IR experiments and simulations" @default.
• W2626388906 cites W1563494356 @default.
• W2626388906 cites W1636236690 @default.
• W2626388906 cites W1912811808 @default.
• W2626388906 cites W1966108258 @default.
• W2626388906 cites W1966702069 @default.
• W2626388906 cites W1974292841 @default.
• W2626388906 cites W1975762035 @default.
• W2626388906 cites W1982219464 @default.
• W2626388906 cites W1984864311 @default.
• W2626388906 cites W1985515789 @default.
• W2626388906 cites W1986000842 @default.
• W2626388906 cites W1987998850 @default.
• W2626388906 cites W1991394389 @default.
• W2626388906 cites W1991794210 @default.
• W2626388906 cites W1993935900 @default.
• W2626388906 cites W1998643104 @default.
• W2626388906 cites W2005901924 @default.
• W2626388906 cites W2006057429 @default.
• W2626388906 cites W2011215428 @default.
• W2626388906 cites W2015624811 @default.
• W2626388906 cites W2017798184 @default.
• W2626388906 cites W2025717854 @default.
• W2626388906 cites W2025814369 @default.
• W2626388906 cites W2027186143 @default.
• W2626388906 cites W2029518596 @default.
• W2626388906 cites W2029860147 @default.
• W2626388906 cites W2038196904 @default.
• W2626388906 cites W2041638382 @default.
• W2626388906 cites W2045768907 @default.
• W2626388906 cites W2047092964 @default.
• W2626388906 cites W2049475242 @default.
• W2626388906 cites W2054134130 @default.
• W2626388906 cites W2055060047 @default.
• W2626388906 cites W2056624015 @default.
• W2626388906 cites W2057944173 @default.
• W2626388906 cites W2060499505 @default.
• W2626388906 cites W2061975878 @default.
• W2626388906 cites W2064141166 @default.
• W2626388906 cites W2065377007 @default.
• W2626388906 cites W2067051784 @default.
• W2626388906 cites W2068644111 @default.
• W2626388906 cites W2069672553 @default.
• W2626388906 cites W2072480847 @default.
• W2626388906 cites W2073421746 @default.
• W2626388906 cites W2075187353 @default.
• W2626388906 cites W2086079563 @default.
• W2626388906 cites W2092758119 @default.
• W2626388906 cites W2097895571 @default.
• W2626388906 cites W2098894422 @default.
• W2626388906 cites W2106140689 @default.
• W2626388906 cites W2120571018 @default.
• W2626388906 cites W2123453296 @default.
• W2626388906 cites W2123526681 @default.
• W2626388906 cites W2125457191 @default.
• W2626388906 cites W2127577365 @default.
• W2626388906 cites W2128097747 @default.
• W2626388906 cites W2140506809 @default.
• W2626388906 cites W2142635246 @default.
• W2626388906 cites W2166530934 @default.
• W2626388906 cites W2289463513 @default.
• W2626388906 cites W2294888750 @default.
• W2626388906 cites W2316735301 @default.
• W2626388906 cites W2318197600 @default.
• W2626388906 cites W2322060739 @default.
• W2626388906 cites W2340237644 @default.
• W2626388906 cites W2399172722 @default.
• W2626388906 cites W2408547592 @default.
• W2626388906 cites W2470841300 @default.
• W2626388906 cites W2523134646 @default.
• W2626388906 cites W2594816406 @default.
• W2626388906 cites W331729359 @default.
• W2626388906 cites W4214503184 @default.
• W2626388906 doi "https://doi.org/10.1063/1.4984766" @default.
• W2626388906 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/28641416" @default.
• W2626388906 hasPublicationYear "2017" @default.
• W2626388906 type Work @default.
• W2626388906 sameAs 2626388906 @default.
• W2626388906 citedByCount "35" @default.
• W2626388906 countsByYear W26263889062017 @default.
• W2626388906 countsByYear W26263889062018 @default.
• W2626388906 countsByYear W26263889062019 @default.
• W2626388906 countsByYear W26263889062020 @default.
• W2626388906 countsByYear W26263889062021 @default.
• W2626388906 countsByYear W26263889062022 @default.
• W2626388906 countsByYear W26263889062023 @default.
• W2626388906 crossrefType "journal-article" @default.
• W2626388906 hasAuthorship W2626388906A5029192239 @default.
• W2626388906 hasAuthorship W2626388906A5050040176 @default.
• W2626388906 hasAuthorship W2626388906A5078149381 @default.
• W2626388906 hasBestOaLocation W26263889061 @default.

• next