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• W2626507083 endingPage "688" @default.
• W2626507083 startingPage "684" @default.
• W2626507083 abstract "The depolymerization of poly(limonene carbonate) (PLC) initiated by 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD) was investigated. The strong organic base TBD was capable of deprotonating the OH-terminated PLC, leading to fast degradation via backbiting reactions at high temperature. An interesting feature of the base-initiated breakdown of PLC lies in the quantitative depolymerization into the corresponding initial limonene oxide monomer. This result implies the complete back-to-monomer recyclability of the fully biobased PLC, which accordingly can be considered as a really sustainable material. Additionally, the stability of PLC when exposed to TBD was enhanced by an end-capping reaction, which further supported the proposed degradation pathway." @default.
• W2626507083 created "2017-06-23" @default.
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• W2626507083 date "2017-06-15" @default.
• W2626507083 modified "2023-10-12" @default.
• W2626507083 title "Unique Base-Initiated Depolymerization of Limonene-Derived Polycarbonates" @default.
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• W2626507083 doi "https://doi.org/10.1021/acsmacrolett.7b00310" @default.
• W2626507083 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35650870" @default.
• W2626507083 hasPublicationYear "2017" @default.
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