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- W2644260591 abstract "The authors report that the addition of an appropriate achiral cocatalyst is important for the regioselectivity (Michael versus aldol additions) in the described reaction. Various cocatalysts with hydrogen bond donors were tested and those with adjacent hydrogen bond donors (i.e. catechol derivatives) provided the best results. NMR experiments showed that the imidazolidinone catalyst likely produced an enamine with E configuration, which was preformed and a competent nucleophile in the Michael addition." @default.
- W2644260591 created "2017-06-30" @default.
- W2644260591 date "2005-10-25" @default.
- W2644260591 modified "2023-09-26" @default.
- W2644260591 title "Enantioselective Organocatalytic Michael Additions of Aldehydes to Enones" @default.
- W2644260591 doi "https://doi.org/10.1055/s-2005-916112" @default.
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