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- W2648923897 abstract "Abstract Described herein is a series of azafluorene ornamented thiazine based novel fused heterocyclic organic dyes TBCPCA-1 , TBCPCA-2 , TBTCPCA-1 and TBTCPCA-2 . Nanocrystalline titania based DSSC performance along with photophysical/electrochemical behaviors of the aforementioned dyes have been examined. Utilizing computational approach, distribution of electrons within the molecules has been explored. The devices possessing the novel fused dyes TBCPCA-1 , TBCPCA-2 , TBTCPCA-1 and TBTCPCA-2 as sensitizers exhibited overall power conversion efficiency range between 6.17 ± 0.4 and 7.97 ± 0.3%. The novel fused heterocyclic organic dyes featuring di- tert -butylazafluorene structural motif such as TBCPCA-1 and TBCPCA-2 exhibit higher power conversion efficiency than the ones carrying sterically congested tetra- tert -butyl-tri(azafluorene) scaffold viz., TBTCPCA-1 and TBTCPCA-2 . Amongst the devices fabricated with the utilization of novel heterocyclic dyes as sensitizers, the device possessing the dye TBCPCA-2 as sensitizer displayed the highest power conversion efficiency of 7.97 ± 0.3% along with a V oc of 745 ± 0.6 mV, a J sc of 16.92 ± 0.3 mA.cm −2 and a ff of 0.67 ± 0.003." @default.
- W2648923897 created "2017-06-30" @default.
- W2648923897 creator A5010697490 @default.
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- W2648923897 creator A5041216956 @default.
- W2648923897 date "2017-08-01" @default.
- W2648923897 modified "2023-10-17" @default.
- W2648923897 title "Azafluorene Ornamented Thiazine Based Novel Fused Heterocyclic Organic Dyes for Competent Molecular Photovoltaics" @default.
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- W2648923897 doi "https://doi.org/10.1016/j.electacta.2017.06.151" @default.
- W2648923897 hasPublicationYear "2017" @default.
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