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- W2650872504 abstract "Developing new structures of hydrogen-producing catalyst is essential to the development of electrochemical water splitting. Tungsten carbide-based materials have been widely investigated recently as promising supports to platinum (Pt) for hydrogen evolution reaction (HER). However, the loading capacity and the fixed stability of Pt are still the main problems to be faced with. Herein we demonstrate a strategy which can be used for mass-production for preparing a thickness-controllable double core-shell [email protected]@Pt structure, based on a half combustion synthesis-carbonation method. By adjusting the carbon content of the precursors, the thickness of carbon layer covering the surface of tungsten carbide and the insertion depth of Pt particles into the carbon layer are controllable during the carbonation process. The carbon layer can fix the platinum particles as well as improve the electrical conductivity. This unique structure maintains a highly efficient and stable catalytic process, leading to its excellent performance for HER with low overpotentials and small Tafel slopes in acidic/alkaline solution. This study provides some guidelines for the large-scale synthesis of nanostructured electrocatalysts." @default.
- W2650872504 created "2017-06-30" @default.
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- W2650872504 date "2018-01-01" @default.
- W2650872504 modified "2023-09-29" @default.
- W2650872504 title "Thickness controllable and mass produced WC@C@Pt hybrid for efficient hydrogen production" @default.
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- W2650872504 doi "https://doi.org/10.1016/j.ensm.2017.06.011" @default.
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