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- W265807677 abstract "The initial thermoelectric power, epsilon/sub theta/, of the cell Ag/AgCl/KCl/AgCl/Ag has been measured from 30 to 90/sup 0/C at KCl molalities of 0.01, 0.005, and 0.001 m. The temperature dependence of epsilon/sub theta/ is consistent with other workers' results, obtained at lower temperatures or higher concentrations, and can be used to establish an absolute or single-ion heat capacity scale, providing the indeterminate single-ion Eastman entropy and heat capacity of transport, S/sup 0/(Cl/sup -/,25/sup 0/C) and C/sub p//sup 0/(Cl/sup -/), can be estimated. Application of the Eastman-Agar expression for the concentration dependence of epsilon/sub theta/ suggests that C/sub p//sup 0/(Cl/sup -/) greater than or equal to C/sub p//sup 0/(KCl)/2. Our epsilon/sub theta/ data, combined with literature values for S/sup 0/(KCl) and C/sub p//sup 0/(KCl), yield a self-consistent ionic scale, s/sup 0/(H/sup +/,25/sup 0/C) = 19.4 +- 2.5 J K/sup -1/mol/sup -1/ and c/sub p//sup 0/(H/sup +/,25/sup 0/C) greater than or equal to -57 J K/sup -1/mol/sup -1/. A more speculative argument, based on the assumption that S/sup 0/(Cl/sup -1/) approx. = S/sup 0/(K/sup +/) at high temperature due to similarities in the secondary waters of hydration and Stokes radii of each ion, suggests that c/sub p//sup 0/(H/sup +/,25/sup 0/C) less thanmore » or equal to 13 J K/sup -1/mol/sup -1/. 5 figures, 1 table.« less" @default.
- W265807677 created "2016-06-24" @default.
- W265807677 creator A5074748535 @default.
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- W265807677 date "1981-07-01" @default.
- W265807677 modified "2023-09-25" @default.
- W265807677 title "Initial thermoelectric power of the silver-silver chloride electrode from 30 to 90.degree.C. An ionic scale for .hivin.Cp.degree. of aqueous electrolytes" @default.
- W265807677 doi "https://doi.org/10.1021/j150614a006" @default.
- W265807677 hasPublicationYear "1981" @default.
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