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- W2667711478 abstract "The microstructure of polymer nanocomposites made with disordered silica filler (Zeosil(R) 1165MP) of industrial relevance and various coating agents is quantitatively analyzed using a combination of SAXS, TEM, and a recently developed structural model. The polymer matrix is formed by an end-functionalized styrene–butadiene statistical copolymer capable of covalent grafting on the silica nanoparticles. The effect of the coating agents with different alkyl chain length (C8, C12, and C18) on filler structure quantified in terms of aggregate formation, for different concentrations (up to 8 wt % with respect to silica), and the effect of a commonly added catalyzer, DPG, are studied using the structural model. As a result, we show that a strongly synergetic effect of both DPG and coating agent exists. Our findings open the road to a fundamental understanding and rational design of model and industrial nanocomposite formulation with optimized coating agents." @default.
- W2667711478 created "2017-06-30" @default.
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- W2667711478 date "2017-06-23" @default.
- W2667711478 modified "2023-10-16" @default.
- W2667711478 title "Synergistic Effect of Small Molecules on Large-Scale Structure of Simplified Industrial Nanocomposites" @default.
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- W2667711478 doi "https://doi.org/10.1021/acs.macromol.7b00954" @default.
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