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- W266940752 abstract "The report describes the results of a study exploring the feasibility of a nonpolluting, combined chemical--electrochemical system for generating electrical power. The process entails the use of coal to reduce lead oxide to a lead in a molten carbonate medium. The lead contained in the molten carbonate is then used in a metal--air electrochemical cell to generate electrical power. To date it has been demonstrated that reduction of lead oxide by solid petroleum coke in a molten sodium--lithium--potassium carbonate eutectic is a two-step process whose overall rate is generally limited by the rate of reaction of solid carbon with CO/sub 2/. The rate of this latter reaction, in turn, is directly proportional to the external surface area of the coke. Under these conditions temperature dependence of the overall process provides an apparent activation energy of about 35 kcal/mole over the temperature range 530 to 650 C. Extrapolation of the results indicates that the feasibility of the concept will not be limited by the kinetics of PbO reduction, only by the kinetics of electrochemical lead oxidation, and indicates that the system could be capable of producing electrical power from coal at 3.4 kWh on the basis of a fuel cost ofmore » $10 per ton i.e., with an overall efficiency of 42 percent.« less" @default.
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- W266940752 date "1973-08-01" @default.
- W266940752 modified "2023-09-27" @default.
- W266940752 title "Pollution-free electrochemical power generation from low grade coal. [Pb/air battery with PbO reduced by coke]" @default.
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