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- W2670890341 abstract "A ligand-free Pd/Cu-catalyzed aminosulfonylation of aryl iodides has been successfully developed. The protocol provides a straightforward approach to access a broad range of structurally intriguing sulfonamides in one pot, at low catalyst loading from the sulfur dioxide surrogate 1,4-diazabicyclo[2.2.2]octane bis(sulfur oxide) (DABSO) and O-benzoyl hydroxylamines under mild conditions. Even without additional ligands, the protocol reveals broad substrate scope for both partners and tolerates all kinds of functional groups. Furthermore, the proposed sulfinate intermediate could be critical for this ligand-free catalytic transformation." @default.
- W2670890341 created "2017-06-30" @default.
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- W2670890341 date "2017-08-15" @default.
- W2670890341 modified "2023-10-16" @default.
- W2670890341 title "Ligand-Free Pd/Cu-Catalyzed Aminosulfonylation of Aryl Iodides for Direct Sulfonamide Syntheses" @default.
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- W2670890341 doi "https://doi.org/10.1002/ajoc.201700350" @default.
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