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- W267273399 abstract "The reaction of the benzylglyoximate complexes of cobalt with bromotrichloromethane leads to the formation of 1,1,1-trichloro-2-arylethanes, which correspond to bimolecular homolytic substitution of the cobalt-containing group by the trichloromethyl radical, as the main reaction products and also the corresponding benzyl bromides. The substitution rate increases with increase in the electron-donating characteristics of the substituents in the aromatic ring. Equimolar additions of pyridine and imidazole have practically no effect on the transformation rate of the complexes." @default.
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- W267273399 date "1988-10-10" @default.
- W267273399 modified "2023-09-23" @default.
- W267273399 title "Effect of structural factors on rate of biomolecular homolytic substitution at a carbon atom in benzyl complexes of cobalt" @default.
- W267273399 hasPublicationYear "1988" @default.
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