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- W2676751488 abstract "Hollow MgFe2O4 cubic particles are synthesized by using metal organic frameworks (MOFs) Prussian blue microcubes as the self-sacrificial templates, and are used as anode material for lithium-ion batteries. The regular MgFe2O4 microboxes are characterized by ~570 nm in size and shells of ~ 100 nm in thickness, which consists of crystallites with an average size of ~ 24 nm. They display an initial discharge capacity of 1278 mAh g−1 and maintain a discharge capacity of 646 mAh g−1 in the 100th cycle at 50 mA g−1. In addition, MgFe2O4 microboxes show a high discharge capacity of 781 mAh g−1 in the 550th cycle at 1.0 A g−1. They also exhibit a low charge-transfer resistance. The superior cycling and rate performance of MgFe2O4 anodes is attributed to their unique cubic hollow structure with porous shells, which facilitates charge transfer and Li+ diffusion. Additionally, the MgO matrix originated from MgFe2O4 decomposition prevents the agglomeration of active Fe and Fe2O3 tiny particles during cycling." @default.
- W2676751488 created "2017-06-30" @default.
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- W2676751488 date "2017-10-01" @default.
- W2676751488 modified "2023-10-15" @default.
- W2676751488 title "MOFs-derived MgFe2O4 microboxes as anode material for lithium-ion batteries with superior performance" @default.
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- W2676751488 doi "https://doi.org/10.1016/j.ceramint.2017.06.124" @default.
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