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• W2681714340 abstract "Diode laser based multi-step resonance ionization mass spectrometry (RIMS), which has been developed primarily for ultra trace analysis of long lived radioactive isotopes has been adapted for the application to elements within the sequence of the rare earths. First investigations concern Gd isotopes. Here high suppression of isobars, as provided by RIMS, is mandatory. Using a three step resonant excitation scheme into an autoionizing state, which has been the subject of preparatory spectroscopic investigations, high efficiency of >1×10−6 and good isobaric selectivity >107 was realized. Additionally the linearity of the method has been demonstrated over six orders of magnitude. Avoiding contaminations from the Titanium-carrier foil resulted in a suppression of background of more than one order of magnitude and a correspondingly low detection limit of 4×109 atoms, equivalent to lpg of Gd. The technique has been applied for trace determination of the Gd-content in animal tissue. Bio-medical micro samples wer..." @default.
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• W2681714340 date "2001-01-01" @default.
• W2681714340 modified "2023-09-23" @default.
• W2681714340 title "Gadolinium trace determination in biomedical samples by diode-laser-based multi-step resonance ionization mass spectrometry" @default.
• W2681714340 doi "https://doi.org/10.1063/1.1405611" @default.
• W2681714340 hasPublicationYear "2001" @default.
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