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- W2681805361 abstract "Abstract Bimetallic Ni-Cu/SAPO-11 catalysts were prepared by co-impregnation method and assessed in the hydroisomerization of n -octane. Their physicochemical properties were characterized by means of powder X-ray diffraction, nitrogen adsorption-desorption, temperature-programmed desorption of ammonia, pyridine-adsorbed infrared spectroscopy, temperature-programmed reduction of hydrogen, transmission electron microscopy, energy dispersive X-ray, and X-ray photoelectron spectroscopy. The Ni-Cu alloy was formed after reduction in the H 2 flow at 450 °C. Copper changed the electronic interaction of nickel and diluted the nickel ensemble size in the Ni-Cu alloy. The hydrogenolysis reaction that decreases the selectivity of isomerization was effectively restrained over the bimetallic Ni-Cu/SAPO-11 catalysts. The selectivity to n -octane isomers over the bimetallic nickel (3%) and copper (1.5%) catalyst was 19% more than that over the monometallic nickel (3%) catalyst at the conversion of 70%. A possible reaction scheme was proposed to explain the catalytic properties in n -octane hydroisomerization." @default.
- W2681805361 created "2017-06-30" @default.
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- W2681805361 date "2017-08-01" @default.
- W2681805361 modified "2023-10-10" @default.
- W2681805361 title "Hydroisomerization of n -octane over bimetallic Ni-Cu/SAPO-11 catalysts" @default.
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- W2681805361 doi "https://doi.org/10.1016/j.apcata.2017.06.028" @default.
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