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- W2685278081 abstract "Dialkyl[1,1-bis(alkylchloroalanyl)organylmethyl]phosphine•dialkylchloroalane(1/1) complexes (1a–1d) were synthesized and fully characterized. In 1a–1d, dative bonding between phosphorus or chlorine as a donor atom and aluminum as an acceptor atom results in a bicyclic system. The 31P{1H} NMR spectra of all compounds dissolved in d6-benzene indicate the presence of several isomers in solution. The 27Al{1H} NMR spectra of 1a–1d dissolved in d6-benzene as well show very broad singlets between 177 and 140 ppm. For all compounds, crystal structures consist of two fused four- and five-membered rings. The 1λ3-phosphaalkyne reacts at the Al–C bond of the starting material, whereas the Al–Cl moiety remains intact. The heterocycle isolated is a molecular complex of the underlying insertion compound and a third equivalent of dialkylaluminum chloride. The four- and five-membered rings both contain two chlorine-bridged aluminum atoms, Al3 and Al1, slightly more symmetrical than that between Al1 and Al6. In the four-membered ring the two aluminum atoms Al1 and Al6 approach each other at an average distance of 289.1 pm which tallies with the element–element distance (286.3 pm) in aluminum metal." @default.
- W2685278081 created "2017-06-30" @default.
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- W2685278081 date "2017-07-03" @default.
- W2685278081 modified "2023-09-27" @default.
- W2685278081 title "Synthesis and crystal structures of dialkyl[1,1-bis(alkylchloroalanyl)organylmethyl]phosphine•dialkylchloroalane(1/1) complexes" @default.
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- W2685278081 doi "https://doi.org/10.1080/00958972.2017.1346248" @default.
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