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- W2689313408 abstract "A series of bis(2-phenylbenzothiozolato-N,C2′)iridium(acetylacetonate) derivatives are developed for use in phosphorescent organic light-emitting diodes (PhOLEDs). Fluorine (-F), trifluoromethyl (-CF3), N-phenylcarbazole-3-yl (-Cz) and diphenylamino (-Ph2N) are incorporated at the 5- or 7-site of the benzothiazole ring to adjust the properties and performance of the complexes. The emitting colors of these iridium phosphors are almost independent of the substituents and the substitution positions, but -F or -CF3 always resulted in increased phosphorescence quantum yields and decreased lifetimes in photoluminescence. Furthermore, the 5-F/CF3-substituted iridium complexes exhibited higher efficiencies than their analogues 7-site isomers in OLEDs. In particular the device based on 1 exhibits a maximum luminance efficiency of 64 cd A−1 (21.3%). Theoretical calculations were performed to interpret the negligible color tuning effect." @default.
- W2689313408 created "2017-06-30" @default.
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- W2689313408 date "2017-10-01" @default.
- W2689313408 modified "2023-10-16" @default.
- W2689313408 title "A strategy to increase phosphorescent efficiency without perturbing emission color for benzothiazole-containing iridium phosphors" @default.
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- W2689313408 doi "https://doi.org/10.1016/j.dyepig.2017.06.048" @default.
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