Matches in SemOpenAlex for { <https://semopenalex.org/work/W269175630> ?p ?o ?g. }
Showing items 1 to 67 of
67
with 100 items per page.
- W269175630 abstract "Over the course of the studies on catalytic deoxygenation of phenolic residues in coal by carbon monoxide, the author performed preliminary investigations into the removal of other heteroatom groups. This report describes the attempted carbonylation of phenyl amido complexes. These studies resulted in the surprisingly facile formation of amidines. The amidine group is the nitrogen analog of carboxylic acids and esters. This functional group combines the properties of an azomethane-like C=N double bond with an amide-like C-N single bond. This group, like the related allyl (C-C-C), aza-allyl (C-N-C), and carboxylato (O-C-O) groups, form a number of transition metal derivatives, with both early and late transition metals. Various bonding modes of the amidino group have been reported. However, most isolated complexes have the amidino ligand as a chelating ligand or bridging two metals. This is due to the preference of amidines to bond via the nitrogen lone pairs, in contrast to the {eta}3 bonding observed in metal-allyl complexes. The experimental section of the paper describes the synthesis of platinum complexes, X-ray diffraction data for one Pt complex, and its reaction with carbon monoxide. Results are presented on the crystal and molecular structure of a platinum complex." @default.
- W269175630 created "2016-06-24" @default.
- W269175630 creator A5000007576 @default.
- W269175630 date "1996-12-31" @default.
- W269175630 modified "2023-10-18" @default.
- W269175630 title "Preconversion catalytic deoxygenation of phenolic functional groups. Quarterly report, January 1--March 30, 1996" @default.
- W269175630 doi "https://doi.org/10.2172/674616" @default.
- W269175630 hasPublicationYear "1996" @default.
- W269175630 type Work @default.
- W269175630 sameAs 269175630 @default.
- W269175630 citedByCount "0" @default.
- W269175630 crossrefType "report" @default.
- W269175630 hasAuthorship W269175630A5000007576 @default.
- W269175630 hasBestOaLocation W2691756303 @default.
- W269175630 hasConcept C106773901 @default.
- W269175630 hasConcept C116569031 @default.
- W269175630 hasConcept C155647269 @default.
- W269175630 hasConcept C161790260 @default.
- W269175630 hasConcept C168382676 @default.
- W269175630 hasConcept C170493617 @default.
- W269175630 hasConcept C178790620 @default.
- W269175630 hasConcept C185592680 @default.
- W269175630 hasConcept C20950531 @default.
- W269175630 hasConcept C2778439535 @default.
- W269175630 hasConcept C2778622868 @default.
- W269175630 hasConcept C2779778602 @default.
- W269175630 hasConcept C2780378348 @default.
- W269175630 hasConcept C512735826 @default.
- W269175630 hasConcept C518104683 @default.
- W269175630 hasConcept C55493867 @default.
- W269175630 hasConcept C71240020 @default.
- W269175630 hasConceptScore W269175630C106773901 @default.
- W269175630 hasConceptScore W269175630C116569031 @default.
- W269175630 hasConceptScore W269175630C155647269 @default.
- W269175630 hasConceptScore W269175630C161790260 @default.
- W269175630 hasConceptScore W269175630C168382676 @default.
- W269175630 hasConceptScore W269175630C170493617 @default.
- W269175630 hasConceptScore W269175630C178790620 @default.
- W269175630 hasConceptScore W269175630C185592680 @default.
- W269175630 hasConceptScore W269175630C20950531 @default.
- W269175630 hasConceptScore W269175630C2778439535 @default.
- W269175630 hasConceptScore W269175630C2778622868 @default.
- W269175630 hasConceptScore W269175630C2779778602 @default.
- W269175630 hasConceptScore W269175630C2780378348 @default.
- W269175630 hasConceptScore W269175630C512735826 @default.
- W269175630 hasConceptScore W269175630C518104683 @default.
- W269175630 hasConceptScore W269175630C55493867 @default.
- W269175630 hasConceptScore W269175630C71240020 @default.
- W269175630 hasLocation W2691756301 @default.
- W269175630 hasLocation W2691756302 @default.
- W269175630 hasLocation W2691756303 @default.
- W269175630 hasOpenAccess W269175630 @default.
- W269175630 hasPrimaryLocation W2691756301 @default.
- W269175630 hasRelatedWork W1458172178 @default.
- W269175630 hasRelatedWork W1527619952 @default.
- W269175630 hasRelatedWork W1971569654 @default.
- W269175630 hasRelatedWork W1999948107 @default.
- W269175630 hasRelatedWork W2063984682 @default.
- W269175630 hasRelatedWork W2067038107 @default.
- W269175630 hasRelatedWork W2082456607 @default.
- W269175630 hasRelatedWork W2280940618 @default.
- W269175630 hasRelatedWork W3074709280 @default.
- W269175630 hasRelatedWork W4213150582 @default.
- W269175630 isParatext "false" @default.
- W269175630 isRetracted "false" @default.
- W269175630 magId "269175630" @default.
- W269175630 workType "report" @default.