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- W27048701 abstract "Equations describing the development of concentrations in an EE two-electron-transfer redox system with comproportionation/disproportionation during electrolysis are solved. The change of the open circuit potential of an indicator electrode under such conditions is analysed as a function of the charge Q transferred and the disproportionation equilibrium constant K . The analysis is valid for arbitrary Q and K . The conditions for a determination of K from experimental data are discussed and compared to earlier analyses in limiting situations. The technique is more sensitive than cyclic voltammetry in cases of compressed potentials." @default.
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- W27048701 date "2002-08-01" @default.
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- W27048701 title "Electroanalytical simulations" @default.
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- W27048701 doi "https://doi.org/10.1016/s0022-0728(02)00997-x" @default.
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