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• W270905588 startingPage "74" @default.
• W270905588 abstract "A new compound [PMo8VIMo4VO40(VIVO)2{Co(phen)2}2](H3O)2[PMo4VIMo8VO40(VIVO)2{Co(phen)2(H2O)}2] 1 (phen = phenanthroline) has been synthesized under hydrothermal conditions and characterized by IR, TG analysis and single-crystal X-ray diffraction. The study of the magnetic property of compound 1 exhibits the presence of antiferromagnetic interactions. Compound 1 crystallizes in the monoclinic system, space group P21/c, a = 21.843(4) Å, b = 16.566(3) Å, c = 21.025(4) Å, α = 90°, β = 100.26(3)°, γ = 90°, V = 7486(3) Å3, Z = 2. The basic building unit in compound 1 is the [PMo12V2O42] cluster. The most remarkable structural feature of 1 is that there exist two distinct [PMo12V2O42] clusters. One is covalently linked by [Co(phen)2] complexes to form 2D covalent layer, the other supports two [Co(phen)2(H2O)] complexes forming a 2D supramolecular network. Such two different kinds of layers are further stacked to form a novel 3D supramolecular framework." @default.
• W270905588 created "2016-06-24" @default.
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• W270905588 date "2007-03-01" @default.
• W270905588 modified "2023-10-18" @default.
• W270905588 title "A novel two-dimensional mixed molybdenum–vanadium polyoxometalate: Synthesis, magnetic property and characterization of" @default.
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• W270905588 doi "https://doi.org/10.1016/j.molstruc.2006.06.007" @default.
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