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- W27138158 abstract "The Process Facility Modification proposed for the Hanford PUREX plant includes control of gaseous radioiodine. In support of the Westinghouse Hanford Company design effort for the PFM, the Pacific Northwest Laboratory has evaluated caustic scrubbing and the use of silver-containing solid sorbents to remove iodine from the dissolver offgas (DOG) stream. The present report describes the behavior of several silver-containing zeolites and silver nitrate-impregnated silicic acid tested under conditions simulating normal and standby operation of the PFM. These studies found that the silver zeolites, Norton silver mordenite (NAgZ), Linde silver mordenite (LAgZ), and partially silver-exchanged Linde silver faujasite (PAgX), can routinely reduce the gaseous iodine concentration in a simulated PFM DOG to <10/sup -5/ ..mu..mol I/L, while a commercially produced silver nitrate-impregnated silicic acid (AgNO/sub 3/Si) could not at these test conditions. Tests simulating standby operation of beds loaded up to 0.25 ..mu..mol I/g sorbent indicate that standby operation will not result in effluent concentrations above 10/sup -5/ ..mu..mol I/L. At higher loadings standby operation initially caused iodine to migrate from NAgZ. There were indications that the iodine tends to stabilize with time, but insufficient information is available to fully characterize these reactions. 4 refs., 2 tabs., 5 figs." @default.
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- W27138158 date "1988-09-01" @default.
- W27138158 modified "2023-09-27" @default.
- W27138158 title "Performance of some silver sorbents for control of radioiodine from nuclear fuel operations" @default.
- W27138158 hasPublicationYear "1988" @default.
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