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- W2715309195 abstract "This article focuses on two-dimensional polymers (2DPs) prepared at air–water interface through dynamic chemistry. The advantages of air–water interface polymerization include easy formation of single layer of organic monomers as well as final polymer product on water surface, possible production of large size monolayer polymer sheet, and green reaction medium. To form monolayer polymer sheet with periodic structural order, the choice of monomer is critical. We discuss monomer design principles, such as geometry, amphiphilicity, and rigidity, which are the most important factors that control the formation of monolayer of monomers at water surface. With properly designed monomers, the polymerization of monolayer monomers through metal–ligand coordination or dynamic covalent reactions (e.g., imine reaction) forms monolayer polymer sheets. The reversible nature of metal–ligand coordination or dynamic covalent reactions can provide error correction mechanism, thus potentially minimizing the formation of defects and improving the structure periodicity. The synthesis and characterization of such metal–organic or covalent–organic 2DPs are discussed in detail. The application of these 2DPs is also briefly discussed." @default.
- W2715309195 created "2017-06-30" @default.
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- W2715309195 date "2018-01-01" @default.
- W2715309195 modified "2023-10-17" @default.
- W2715309195 title "Two-Dimensional Polymer Synthesis by Dynamic Chemistry at the Air–Water Interface" @default.
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- W2715309195 doi "https://doi.org/10.1016/b978-0-12-409547-2.13121-x" @default.
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