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• W2715600406 endingPage "7706" @default.
• W2715600406 startingPage "7694" @default.
• W2715600406 abstract "The reaction of uranyl nitrate with terephthalic acid (H2TP) under hydrothermal conditions in the presence of an organic base, 1,3-(4,4′-bispyridyl)propane (BPP) or 4,4′-bipyridine (BPY), provided four uranyl terephthalate compounds with different entangled structures by a pH-tuning method. [UO2(TP)1.5](H2BPP)0.5·2H2O (1) obtained in a relatively acidic solution (final aqueous pH, 4.28) crystallizes in the form of a noninterpenetrated honeycomb-like two-dimensional network structure. An elevation of the solution pH (final pH, 5.21) promotes the formation of a dimeric uranyl-mediated polycatenated framework, [(UO2)2(μ-OH)2(TP)2]2(H2BPP)2·4.5H2O (2). Another new polycatenated framework with a monomeric uranyl unit, [(UO2)2(TP)3](H2BPP) (3), begins to emerge as a minor accompanying product of 2 when the pH is increased up to 6.61, and turns out to be a significant product at pH 7.00. When more rigid but small-size BPY molecules replace BPP molecules, [UO2(TP)1.5](H2BPP)0.5 (4) with a polycatenated framework similar to 3 was obtained in a relatively acidic solution (final pH, 4.81). The successful preparation of 2–4 represents the first report of uranyl–organic polycatenated frameworks derived from a simple H2TP linker. A direct comparison between these polycatenated frameworks and previously reported uranyl terephthalate compounds suggests that the template and cavity-filling effects of organic bases (such as BPP or BPY), in combination with specific hydrothermal conditions, promote the formation of uranyl terephthalate polycatenated frameworks." @default.
• W2715600406 created "2017-06-30" @default.
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• W2715600406 date "2017-06-23" @default.
• W2715600406 modified "2023-10-15" @default.
• W2715600406 title "Exploring New Assembly Modes of Uranyl Terephthalate: Templated Syntheses and Structural Regulation of a Series of Rare 2D → 3D Polycatenated Frameworks" @default.
• W2715600406 cites W1770636547 @default.
• W2715600406 cites W1837636642 @default.
• W2715600406 cites W1935161090 @default.
• W2715600406 cites W1969915624 @default.
• W2715600406 cites W1971818787 @default.
• W2715600406 cites W1978061701 @default.
• W2715600406 cites W1978659336 @default.
• W2715600406 cites W1984825047 @default.
• W2715600406 cites W1985568020 @default.
• W2715600406 cites W1987239169 @default.
• W2715600406 cites W1987518733 @default.
• W2715600406 cites W1993122987 @default.
• W2715600406 cites W1995062269 @default.
• W2715600406 cites W1999611654 @default.
• W2715600406 cites W2000379890 @default.
• W2715600406 cites W2012201701 @default.
• W2715600406 cites W2015197151 @default.
• W2715600406 cites W2015697056 @default.
• W2715600406 cites W2016392167 @default.
• W2715600406 cites W2023271753 @default.
• W2715600406 cites W2024315283 @default.
• W2715600406 cites W2031649562 @default.
• W2715600406 cites W2034803152 @default.
• W2715600406 cites W2036346352 @default.
• W2715600406 cites W2038767330 @default.
• W2715600406 cites W2040441542 @default.
• W2715600406 cites W2047203881 @default.
• W2715600406 cites W2050175951 @default.
• W2715600406 cites W2052530292 @default.
• W2715600406 cites W2059205366 @default.
• W2715600406 cites W2059392874 @default.
• W2715600406 cites W2060728601 @default.
• W2715600406 cites W2071588941 @default.
• W2715600406 cites W2086288648 @default.
• W2715600406 cites W2089708541 @default.
• W2715600406 cites W2091880182 @default.
• W2715600406 cites W2093018676 @default.
• W2715600406 cites W2105649693 @default.
• W2715600406 cites W2106673302 @default.
• W2715600406 cites W2131350133 @default.
• W2715600406 cites W2132454074 @default.
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• W2715600406 cites W2145538332 @default.
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• W2715600406 cites W2178094572 @default.
• W2715600406 cites W2180249341 @default.
• W2715600406 cites W2232505242 @default.
• W2715600406 cites W2287210240 @default.
• W2715600406 cites W2294348160 @default.
• W2715600406 cites W2300457072 @default.
• W2715600406 cites W2313964968 @default.
• W2715600406 cites W2314986821 @default.
• W2715600406 cites W2315839291 @default.
• W2715600406 cites W2319178167 @default.
• W2715600406 cites W2321009623 @default.
• W2715600406 cites W2321935457 @default.
• W2715600406 cites W2326783590 @default.
• W2715600406 cites W2331544626 @default.
• W2715600406 cites W2332714924 @default.
• W2715600406 cites W2334013383 @default.
• W2715600406 cites W2334925536 @default.
• W2715600406 cites W2340273043 @default.
• W2715600406 cites W2367048215 @default.
• W2715600406 cites W2388100558 @default.
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• W2715600406 cites W2475292620 @default.
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• W2715600406 doi "https://doi.org/10.1021/acs.inorgchem.7b00312" @default.
• W2715600406 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/28644618" @default.
• W2715600406 hasPublicationYear "2017" @default.
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