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- W2725003065 abstract "In this work, a facile and in situ method is proposed to prepare a high-performance photoanode with an ultrathin Fe2TiO5 layer on hematite by the reaction of tetrabutyl titanate with electro-reduced Fe film, which avoids using FeOOH film as substrate. The preparation involves 30 s of direct electro-reduction (ER) of Fe film and 3 min of a sol method, followed by thermal treatment. The as-prepared photoanode shows a significant enhancement of the photocurrent density to ∼2.0 mA/cm2 (1.23 V vs. RHE). The incorporation of a Co/Pi catalyst resulted in a photocurrent density of ∼3.05 mA/cm2. The high photoelectrochemical performance can be attributed to the low microstructural defects, the better carrier separation and faster electron transfer based on electrochemical impedance spectroscopy (EIS) and Intensity-modulated photocurrent spectroscopy (IMPS) analysis. In addition, the prepared photoanode shows good stability under both alkaline and neutral conditions." @default.
- W2725003065 created "2017-07-14" @default.
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- W2725003065 date "2017-12-01" @default.
- W2725003065 modified "2023-10-17" @default.
- W2725003065 title "Preparation of hematite with an ultrathin iron titanate layer via an in situ reaction and its stable, long-lived, and excellent photoelectrochemical performance" @default.
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- W2725003065 doi "https://doi.org/10.1016/j.apcatb.2017.07.012" @default.
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