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- W2726277252 abstract "Nanocrystalline Pr 1-x Zr x O 2-δ (0 ≤ x ≤ 1) and Pr 1-x-y Pd y Zr x O 2-δ (x = 0.50, y = 0.02) solid solutions have been synthesized by a single step solution combustion method. The whole range of solid solution compositions crystallize in cubic fluorite structure. The lattice parameter 'a' linearly varied up to x = 1.0. Oxygen-storage capacity (OSC) and redox properties of Pr 1-x Zr x O 2-δ (0.0 ≤ x ≤ 0.8) solid solutions have been investigated by temperature-programmed reduction (TPR) and are compared with those of Ce 1-x Zr x O 2 . Pr 1-x Zr x O 2-δ exhibited H 2 uptake and CO oxidation at a lower temperature than Ce 1-x Zr x O 2 . Small amount of Pd ion (y = 0.02) substitution was found to bring down the temperature of oxygen release-storage significantly." @default.
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- W2726277252 date "2008-10-02" @default.
- W2726277252 modified "2023-09-29" @default.
- W2726277252 title "Synthesis, structure and oxygen-storage capacity of Pr 1-x Zr x O 2-δ and Pr 1-x-y Pd y Zr x O 2-δ" @default.
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