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• W2726563495 abstract "A computational fluid dynamics (CFD) approach coupled with polymerization kinetics is implemented to investigate styrene polymerization using azobisisobutyronitrile (AIBN) as initiator and toluene as solvent in a lab-scale continuous stirred tank reactor (CSTR). The integration of kinetic model and CFD model taking molecular weight distribution into consideration is accomplished by a user-defined function (UDF) code using the method of moments. The results predicted by CFD compare with literature data satisfactorily. The effects of operating variables such as species diffusion coefficient, impeller speed, residence time and reaction temperature are analyzed. As the impeller speed increases, the degree of mixing homogeneity is improved, which results in decreasing conversion and molecular weight distribution. The proposed method can be used to predict polymerization behaviors in non-ideal mixing industrial reactors." @default.
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• W2726563495 date "2017-09-01" @default.
• W2726563495 modified "2023-10-02" @default.
• W2726563495 title "CFD modeling of styrene polymerization in a CSTR" @default.
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• W2726563495 doi "https://doi.org/10.1016/j.cherd.2017.06.028" @default.
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