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- W2726630122 abstract "A novel and concise C5-alkylation of oxazoles using alkylboronic acids as alkyl donors via Pd(ii)-catalysed C-H bond activation has been achieved in moderate to good yields with satisfactory functional group tolerance. Instead of commonly used BQ as a key promoter, DDQ was discovered to be a better additive that significantly promoted this alkylation. This efficient and advanced method represents the first C(sp2)-C(sp3) cross-coupling reaction at the C5-position of oxazoles, which is particularly attractive due to its potential applications in the late-stage functionalization of oxazole-containing bioactive molecules." @default.
- W2726630122 created "2017-07-14" @default.
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- W2726630122 date "2017-01-01" @default.
- W2726630122 modified "2023-10-01" @default.
- W2726630122 title "DDQ-promoted direct C5-alkylation of oxazoles with alkylboronic acids via palladium-catalysed C–H bond activation" @default.
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- W2726630122 doi "https://doi.org/10.1039/c7ob01083d" @default.
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