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- W2726946585 abstract "The design, synthesis, and structural characterization of a new anionic metal-organic framework, namely, {(H2N(Me)2)[Cu(bidc)](H2O)3}n (1), with 1D helical metal chains is reported here. The title complex was synthesized by solvothermal reaction of Cu(NO3)2·3H2O and benzimidazole-5,6-dicarboxylic acid (H3bidc) in a mixed solvent of DMF, 1,4-dioxane, H2O and HNO3 (aq) at 120 °C for three days, which reveals a 3D porous framework with 1D nanotubular channels running along the c axis. The pore characteristics and gas sorption properties of this compound were investigated at both cryogenic temperature and room temperature by experimentally measuring N2, CH4 and CO2 adsorption/desorption isotherms. The amount of the N2 and CO2 uptake is 146 cm3/g at 77 K and 52 cm3/g at 273 K, which is the highest among MOFs constructed from the H3bidc ligand. In addition the activated 1 shows high adsorption selectivity of CO2 over CH4 at room temperature." @default.
- W2726946585 created "2017-07-14" @default.
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- W2726946585 date "2017-09-01" @default.
- W2726946585 modified "2023-09-27" @default.
- W2726946585 title "Microporous metal–organic framework with 1D helical chain building units: Synthesis, structure and gas sorption properties" @default.
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- W2726946585 doi "https://doi.org/10.1016/j.inoche.2017.07.003" @default.
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