Matches in SemOpenAlex for { <https://semopenalex.org/work/W2727298719> ?p ?o ?g. }
Showing items 1 to 56 of
56
with 100 items per page.
- W2727298719 endingPage "0513" @default.
- W2727298719 startingPage "0513" @default.
- W2727298719 abstract "Trifluoromethyl-substituted, enantioenriched cyclopropanes can provide access to chiral building blocks for new drug candidates; however, only a few synthetic approaches towards these compounds have been reported so far. In this paper, a highly enantio- and diastereoselective cobalt-catalyzed cyclopropanation of alkenes with F3CCHN2 is reported. Importantly, the reaction was carried out in aqueous media. The methodology tolerates a wide range of styrenes, including 1,1-disubstituted derivatives. Diastereoselectivities up to 180:1 in favor of the trans adduct were observed, accompanied with enantioselectivities of 86-94% ee." @default.
- W2727298719 created "2017-07-14" @default.
- W2727298719 date "2011-04-15" @default.
- W2727298719 modified "2023-09-25" @default.
- W2727298719 title "Enantioselective Synthesis of Trifluoromethyl-Substituted Cyclopropanes" @default.
- W2727298719 doi "https://doi.org/10.1055/s-0030-1259876" @default.
- W2727298719 hasPublicationYear "2011" @default.
- W2727298719 type Work @default.
- W2727298719 sameAs 2727298719 @default.
- W2727298719 citedByCount "0" @default.
- W2727298719 crossrefType "journal-article" @default.
- W2727298719 hasBestOaLocation W27272987192 @default.
- W2727298719 hasConcept C108204754 @default.
- W2727298719 hasConcept C146686406 @default.
- W2727298719 hasConcept C161790260 @default.
- W2727298719 hasConcept C178790620 @default.
- W2727298719 hasConcept C185592680 @default.
- W2727298719 hasConcept C21951064 @default.
- W2727298719 hasConcept C2776442012 @default.
- W2727298719 hasConcept C2777052750 @default.
- W2727298719 hasConcept C2780263894 @default.
- W2727298719 hasConcept C515602321 @default.
- W2727298719 hasConcept C71240020 @default.
- W2727298719 hasConceptScore W2727298719C108204754 @default.
- W2727298719 hasConceptScore W2727298719C146686406 @default.
- W2727298719 hasConceptScore W2727298719C161790260 @default.
- W2727298719 hasConceptScore W2727298719C178790620 @default.
- W2727298719 hasConceptScore W2727298719C185592680 @default.
- W2727298719 hasConceptScore W2727298719C21951064 @default.
- W2727298719 hasConceptScore W2727298719C2776442012 @default.
- W2727298719 hasConceptScore W2727298719C2777052750 @default.
- W2727298719 hasConceptScore W2727298719C2780263894 @default.
- W2727298719 hasConceptScore W2727298719C515602321 @default.
- W2727298719 hasConceptScore W2727298719C71240020 @default.
- W2727298719 hasIssue "05" @default.
- W2727298719 hasLocation W27272987191 @default.
- W2727298719 hasLocation W27272987192 @default.
- W2727298719 hasOpenAccess W2727298719 @default.
- W2727298719 hasPrimaryLocation W27272987191 @default.
- W2727298719 hasRelatedWork W2052040736 @default.
- W2727298719 hasRelatedWork W2055190992 @default.
- W2727298719 hasRelatedWork W2094716250 @default.
- W2727298719 hasRelatedWork W2112705984 @default.
- W2727298719 hasRelatedWork W2154956352 @default.
- W2727298719 hasRelatedWork W2603561992 @default.
- W2727298719 hasRelatedWork W2606296176 @default.
- W2727298719 hasRelatedWork W2921114962 @default.
- W2727298719 hasRelatedWork W3184086332 @default.
- W2727298719 hasRelatedWork W4254282951 @default.
- W2727298719 hasVolume "2011" @default.
- W2727298719 isParatext "false" @default.
- W2727298719 isRetracted "false" @default.
- W2727298719 magId "2727298719" @default.
- W2727298719 workType "article" @default.