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• W2728462216 endingPage "622" @default.
• W2728462216 startingPage "607" @default.
• W2728462216 abstract "The management and disposal of solid waste is of increasing concern across the globe. Hydrothermal processing of sludge has been suggested as a promising solution to deal with the considerable amounts of sludge produced worldwide. Such a process not only degrades organic compounds and reduces waste volume, but also provides an opportunity to recover valuable substances. Hydrothermal processing comprises two main sub-processes: wet oxidation (WO) and thermal hydrolysis (TH), in which the formation of various free radicals results in the production of different intermediates. Volatile fatty acids (VFAs), especially acetic acid, are usually the main intermediates which remain as a by-product of the process. This paper aims to review the fundamental mechanism for hydrothermal processing of sludge, and the formation of different free radicals and intermediates therein. In addition, the proposed kinetic models for the two processes (WO and TH) from the literature are reviewed and the advantages and disadvantages of each model are outlined. The effect of mass transfer as a critical component of the design and development of the processes, which has been neglected in most of these proposed models, is also reviewed, and the effect of influencing parameters on the processes' controlling step (reaction or mass transfer) is discussed." @default.
• W2728462216 created "2017-07-14" @default.
• W2728462216 creator A5000158706 @default.
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• W2728462216 creator A5019171982 @default.
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• W2728462216 creator A5072560200 @default.
• W2728462216 date "2017-10-01" @default.
• W2728462216 modified "2023-09-27" @default.
• W2728462216 title "Fundamental mechanisms and reactions in non-catalytic subcritical hydrothermal processes: A review" @default.
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• W2728462216 doi "https://doi.org/10.1016/j.watres.2017.06.069" @default.
• W2728462216 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/28709105" @default.
• W2728462216 hasPublicationYear "2017" @default.
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