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- W2728574250 abstract "The nature and structure invertible polymers (AIPs) was substantiated in order to develop polymeric platforms for new drug delivery systems. Synthetic routes to amphiphilic invertible polyesters (AIPEs) based on dicarboxylic acids and polyether diols (i.e., polyethylene glycol and polytetrahydrofuran), as well as to segmented amphiphilic invertible polyurethanes (AIPUs) based on polyether diols and 2,4-tolylene diisocyanate were elaborated via a systematic study of step-growth polymerizations. The effect of reaction conditions on the course of the reactions and the macromolecular configuration of the AIPs was revealed. The targeted synthesis of the AIPs allows for tuning invertible, colloidal, and other physicochemical properties via the design of repeat units and macromolecular configuration. A simple approach to the formation of micellar nanoassemblies from AIPs in an aqueous medium was developed. The concept of tuning invertibility of the nanoassemblies, that is, the ability to change the macromolecular conformation in response to changes in the medium polarity, was developed. The micellar nanoassemblies based on the AIPs are prospective candidates for the delivery of lipophilic drugs. Polymeric drug delivery systems from AIPs are non-toxic, biodegradable, and able to cross physiological barriers. Additionally, they possess invertibility that broadens the potential for targeted delivery and distinguishes them from other delivery systems." @default.
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- W2728574250 date "2017-06-30" @default.
- W2728574250 modified "2023-09-23" @default.
- W2728574250 title "Synthesis of Amphiphilic Invertible Polymers for Biomedical Applications" @default.
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- W2728574250 doi "https://doi.org/10.1002/9781118967904.ch17" @default.
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