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- W2729122999 abstract "Abstract Silks are protein-based natural structured materials with an unusual combination of high strength and elongation. Their unique microstructural features composed of hard β-sheet crystals aligned within a soft amorphous region lead to the robust properties of silks. Herein we report a large enhancement in the intrinsic properties of silk through the transformation of the basic building blocks into a poly-hexagonal carbon structure by a simple heat treatment with axial stretching. The carbon clusters originating from the β-sheet retain the preferred orientation along the fibre axis, resulting in a long-range-ordered graphitic structure by increasing heat-treatment temperatures and leading improvements in mechanical properties with a maximum strength and modulus up to ∼2.6 and ∼470 GPa, respectively, almost four and thirty times surpassing those of raw silk. Moreover, the formation of sp 2 carbon configurations induce a significant change in the electrical properties (e.g. an electrical conductivity up to 4.37 × 10 3 S cm −1 )." @default.
- W2729122999 created "2017-07-14" @default.
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- W2729122999 date "2017-07-13" @default.
- W2729122999 modified "2023-10-11" @default.
- W2729122999 title "Ultra strong pyroprotein fibres with long-range ordering" @default.
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- W2729122999 doi "https://doi.org/10.1038/s41467-017-00132-3" @default.
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