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- W2732556857 abstract "The hydrogenation of functionalized nitroarenes to the corresponding anilines is of great importance in the fine chemical industry and requires high-performance catalysts with a good activity and selectivity. Herein, hydrogenated MoOx (H-MoOx) supported bimetallic Pt-Sn (Pt-Sn/H-MoOx) was developed to accomplish selective and efficient hydrogenation. In the case of 4-nitrostyrene, an outstanding selectivity to 4-vinylaniline (≈93 %) with a high turnover frequency (0.094 s−1) was achieved under mild conditions (T=30 °C, PH2 =1 atm). The metal–support interactions contributed to the efficient turnover on the ultrafine nanoparticles, and the atom-rearranged bimetallic Pt-Sn surface promoted the selectivity because of the preferred adsorption of the nitro group. The good efficiency for various functionalized nitroarenes further verified the promise of Pt-Sn/H-MoOx in chemoselective hydrogenation." @default.
- W2732556857 created "2017-07-14" @default.
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- W2732556857 date "2017-10-12" @default.
- W2732556857 modified "2023-10-08" @default.
- W2732556857 title "Bimetallic Platinum-Tin Nanoparticles on Hydrogenated Molybdenum Oxide for the Selective Hydrogenation of Functionalized Nitroarenes" @default.
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- W2732556857 doi "https://doi.org/10.1002/cctc.201700880" @default.
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