Matches in SemOpenAlex for { <https://semopenalex.org/work/W2732912250> ?p ?o ?g. }
- W2732912250 endingPage "3225" @default.
- W2732912250 startingPage "3218" @default.
- W2732912250 abstract "Novel polymeric solid catalysts, Au@(polythiophene–polythiophene oxides) (Au@PTh–PThOx, x=1–2), are prepared by chemical over-oxidative polymerization of thiophene in the presence of Au nanoparticles. These organocatalysts show significantly higher activity than their liquid analogs (i.e., DMSO, a frequently-used solvent and catalyst) for the catalytic dehydration of fructose into 5-hydroxymethylfurfural (HMF) and exhibit a complete inhibiting effect on HMF rehydration to undesired levulinic acid in low-boiling solvents. We demonstrate that the sulfoxide (-SO) group in Au@PTh–PThOx is more active than the sulfone (-SO2) group, although the formation of the former could be maximized by lowering the concentration of surfactant or improving the concentration of oxidant used in catalyst preparation. The highest HMF yields of 72.6 % and 39.7 % are achieved over Au@PTh–PThO catalyst in 1,4-dioxane and water, respectively. This catalyst could be completely recycled for use in water without activity loss." @default.
- W2732912250 created "2017-07-14" @default.
- W2732912250 creator A5003877423 @default.
- W2732912250 creator A5039997114 @default.
- W2732912250 creator A5048671077 @default.
- W2732912250 creator A5063072196 @default.
- W2732912250 creator A5063490973 @default.
- W2732912250 creator A5091009478 @default.
- W2732912250 date "2017-07-03" @default.
- W2732912250 modified "2023-10-18" @default.
- W2732912250 title "Catalytic Dehydration of Fructose into 5-Hydroxymethylfurfural by a DMSO-like Polymeric Solid Organocatalyst" @default.
- W2732912250 cites W1091462010 @default.
- W2732912250 cites W1791135210 @default.
- W2732912250 cites W1845525212 @default.
- W2732912250 cites W1926844950 @default.
- W2732912250 cites W1964095853 @default.
- W2732912250 cites W1968392170 @default.
- W2732912250 cites W1968730267 @default.
- W2732912250 cites W1975914784 @default.
- W2732912250 cites W1981636018 @default.
- W2732912250 cites W1983566725 @default.
- W2732912250 cites W1983683645 @default.
- W2732912250 cites W1986737281 @default.
- W2732912250 cites W1987676671 @default.
- W2732912250 cites W1994768573 @default.
- W2732912250 cites W1996116239 @default.
- W2732912250 cites W2003377788 @default.
- W2732912250 cites W2010264908 @default.
- W2732912250 cites W2011180893 @default.
- W2732912250 cites W2013783818 @default.
- W2732912250 cites W2020186674 @default.
- W2732912250 cites W2022176651 @default.
- W2732912250 cites W2025012426 @default.
- W2732912250 cites W2027095027 @default.
- W2732912250 cites W2031926173 @default.
- W2732912250 cites W2037661249 @default.
- W2732912250 cites W2040913279 @default.
- W2732912250 cites W2045135100 @default.
- W2732912250 cites W2054549093 @default.
- W2732912250 cites W2056092529 @default.
- W2732912250 cites W2057011165 @default.
- W2732912250 cites W2058252920 @default.
- W2732912250 cites W2064365088 @default.
- W2732912250 cites W2066146543 @default.
- W2732912250 cites W2067240772 @default.
- W2732912250 cites W2075001285 @default.
- W2732912250 cites W2077456833 @default.
- W2732912250 cites W2086872453 @default.
- W2732912250 cites W2088408995 @default.
- W2732912250 cites W2108204845 @default.
- W2732912250 cites W2114806835 @default.
- W2732912250 cites W2123457457 @default.
- W2732912250 cites W2136757198 @default.
- W2732912250 cites W2140393336 @default.
- W2732912250 cites W2141355109 @default.
- W2732912250 cites W2143781908 @default.
- W2732912250 cites W2147405113 @default.
- W2732912250 cites W2150962987 @default.
- W2732912250 cites W2152313391 @default.
- W2732912250 cites W2163156526 @default.
- W2732912250 cites W2166492504 @default.
- W2732912250 cites W2210409354 @default.
- W2732912250 cites W2288875092 @default.
- W2732912250 cites W2294955281 @default.
- W2732912250 cites W2302766018 @default.
- W2732912250 cites W2309871934 @default.
- W2732912250 cites W2323331193 @default.
- W2732912250 cites W2326419922 @default.
- W2732912250 cites W2404571206 @default.
- W2732912250 cites W2491245928 @default.
- W2732912250 cites W2526272818 @default.
- W2732912250 cites W2549879802 @default.
- W2732912250 cites W2564271565 @default.
- W2732912250 cites W2567917141 @default.
- W2732912250 cites W2586895783 @default.
- W2732912250 doi "https://doi.org/10.1002/cctc.201700136" @default.
- W2732912250 hasPublicationYear "2017" @default.
- W2732912250 type Work @default.
- W2732912250 sameAs 2732912250 @default.
- W2732912250 citedByCount "24" @default.
- W2732912250 countsByYear W27329122502017 @default.
- W2732912250 countsByYear W27329122502018 @default.
- W2732912250 countsByYear W27329122502019 @default.
- W2732912250 countsByYear W27329122502020 @default.
- W2732912250 countsByYear W27329122502021 @default.
- W2732912250 countsByYear W27329122502022 @default.
- W2732912250 countsByYear W27329122502023 @default.
- W2732912250 crossrefType "journal-article" @default.
- W2732912250 hasAuthorship W2732912250A5003877423 @default.
- W2732912250 hasAuthorship W2732912250A5039997114 @default.
- W2732912250 hasAuthorship W2732912250A5048671077 @default.
- W2732912250 hasAuthorship W2732912250A5063072196 @default.
- W2732912250 hasAuthorship W2732912250A5063490973 @default.
- W2732912250 hasAuthorship W2732912250A5091009478 @default.
- W2732912250 hasConcept C133495861 @default.
- W2732912250 hasConcept C161790260 @default.
- W2732912250 hasConcept C178790620 @default.
- W2732912250 hasConcept C185592680 @default.