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- W2733388049 abstract "The Cu(I)/phosphoric acid (PA) dual-catalyzed radical aminoperfluoroalkylation and aminodifluoromethylation of alkenes with commercially available fluoroalkylsulfonyl chlorides as the radical source is described. Functionalized α-tertiary pyrrolidines bearing four types of fluoroalkyl groups are obtained with moderate to excellent yields. The introduction of a Cu(I)/phosphoric acid dual catalytic system and the use of silver carbonate as a key additive to inhibit the side hydroamination reaction caused by the in situ generated HCl are crucial for the transformation." @default.
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- W2733388049 date "2017-06-29" @default.
- W2733388049 modified "2023-10-18" @default.
- W2733388049 title "Catalytic Radical Intramolecular Aminoperfluoroalkylation and Aminodifluoromethylation of Unactivated Alkenes with Fluoroalkylsulfonyl Chlorides" @default.
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- W2733388049 doi "https://doi.org/10.1055/s-0036-1589044" @default.
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