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- W2734632483 abstract "Three three-dimensional (3D) heterometallic lanthanide-transition-metal (hetero-Ln-TM) compounds with the formula [Ln6(Cu4Br3)(Cu2Br2)2(Cu2Br)(IN)20(H2O)12]·2H2O [Ln = Gd (1), Ln = Sm (2), Ln = Eu (3)] based on the linkages of one-dimensional Ln organic chain and CumBrn units were synthesized by mixing Ln2O3 with isonicotinic acid (HIN = pyridine-4-carboxylic acid) under hydrothermal condition. During the synthesis, two ligands were used: the isonicotinate (IN–) stabilizes the cluster and links the one-dimensional Ln organic chains and CumBrn motif, whereas Br– anions play a very important role in the formation of the distinct CumBrn units. It is interesting that there are three different Cu-Br motifs: a closed four-membered ring [Cu2Br2] subunit, a linear [Cu2Br] subunit, an S-sharp [Cu4Br3] subunit. Strong fluorescence of compounds 2 and 3 suggests an efficient energy transfer from the ligand to Eu3+ ions. The luminescent investigation indicates that 2 and 3 are excellent candidates for fluorescent materials." @default.
- W2734632483 created "2017-07-21" @default.
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- W2734632483 date "2017-07-17" @default.
- W2734632483 modified "2023-09-27" @default.
- W2734632483 title "Solvothermal Synthesis, Crystal Structure, and Luminescent Properties of Three Heterometallic Lanthanide-Transition-Metal Frameworks Constructed from Three Types of CuBr Motifs" @default.
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- W2734632483 doi "https://doi.org/10.1002/zaac.201700168" @default.
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