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- W2734854900 abstract "The fast atom bombardment (FAB) mass spectral features of pipecuronium bromide (Arduan), used in anaesthesiology as a neuromuscular blocking agent, and seventeen of its related mono-, bis- and tris-quaternary derivatives of general formula Cn+(A−)n (n=1−3) were studied. The +FAB mass spectra of these ammonium salts were found to be very interesting and structurally informative: they exhibit abundant, stable Cn+ ions, i.e. C+, C2+ and even C3+ intact cations for mono-, bis- and trisquaternary salts, respectively. Primary and singly charged Cn+ (A−)n−1 cluster ions were found to be dominant or significant in the spectra for all of these salts showing characteristic decomposition. The −FAB spectra display pronounced Cn+ (A−)n+1 primary cluster ions with a low extent of fragmentation. 252Cf plasma desorption mass spectra of these salts were found to be very similar to those obtained by FAB." @default.
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- W2734854900 date "1990-01-01" @default.
- W2734854900 modified "2023-10-17" @default.
- W2734854900 title "Fast atom bombardment mass spectrometry of quaternary salts of some aminoandrostanes" @default.
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- W2734854900 doi "https://doi.org/10.1016/s0003-2670(00)83659-4" @default.
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