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- W2734870654 abstract "Stoichiometry of Pd(II) interactions with dl-homocystine and 3,3′-dithiodipropionic acid were investigated spectrophotometrically in strong hydrochloric acidic media. It was established that thiolate and sulfinate complexes are products of a disulfide bond cleavage. It is shown that formation of S,S′-binuclear complexes is necessary for the disproportionation reaction. A multi-spectroscopic (UV-Vis, Raman, NMR, EXAFS) investigation on a disulfide bond state in organic disulfides in complexation processes with Pd(II) was developed. A DFT study on geometry of forming complex species was performed." @default.
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- W2734870654 date "2017-07-03" @default.
- W2734870654 modified "2023-10-18" @default.
- W2734870654 title "Reactions of dl-homocystine and 3,3′-dithiodipropionic acid with Pd(II) in aqueous hydrochloric solutions. Part I: coordination model" @default.
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- W2734870654 doi "https://doi.org/10.1080/00958972.2017.1353083" @default.
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