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• W2734980212 abstract "ABSTRACTA new 3-trifluoromethyl-substituted triphenylamine-containing aromatic diacid monomer, N,N-bis(4-carboxyphenyl)-3-trifluoromethylaniline, was prepared by the substitution reaction of 3-trifluoromethylaniline with 4-fluorobenzonitrile, followed by alkaline hydrolysis of the dinitrile intermediate. Novel aromatic polyamides with 3-trifluoromethyl-substituted triphenylamine moieties were prepared from the diacid and various aromatic diamines via the direct phosphorylation polycondensation. All the polyamides were amorphous and readily soluble in many polar organic solvents such as N,N-dimethylacetamide and N-methyl-2-pyrrolidone, and could be solution-cast into transparent, tough, and flexible films with good mechanical properties. They exhibited good thermal stability with relatively high glass-transition temperatures (258–327°C), 10% weight-loss temperatures above 500°C, and char yields higher than 60% at 800°C in nitrogen. These polymers had low dielectric constants of 3.22–3.70 (100 Hz), low mois..." @default.
• W2734980212 created "2017-07-21" @default.
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• W2734980212 date "2017-07-13" @default.
• W2734980212 modified "2023-09-25" @default.
• W2734980212 title "Synthesis and characterization of novel aromatic polyamides containing 3-trifluoromethyl-substituted triphenylamine" @default.
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• W2734980212 doi "https://doi.org/10.1080/10601325.2017.1320769" @default.
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