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• W2735048948 abstract "Abstract 13 C NMR analysis of poly(4-methyl-1,3-pentadiene) (poly(4-MPD)) obtained by using the C 2 symmetric zirconocene based catalytic system: rac -[CH 2 (3- tert -butyl-1-indenyl) 2 ]ZrCl 2 ( 1 )/ 13 C enriched methylaluminoxane (MAO) shows strong differences between the microstructure of the first inserted monomer unit and the in-chain inserted ones. The first insertion step results regiospecific, but not stereospecific, while the propagation step is regio- and stereoselective producing 1,2 syndiotactic poly(4-MPD). This feature is justified by assuming a “chain end” controlled mechanism working for the propagation step of polymerization. 13 C NMR analysis of isotactic poly(4-methyl-1-pentene) (poly(4-MP)) obtained by using the same catalytic system shows that the first monomer insertion is partially enantioselective." @default.
• W2735048948 created "2017-07-21" @default.
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• W2735048948 date "2017-09-01" @default.
• W2735048948 modified "2023-09-23" @default.
• W2735048948 title "Polymerization mechanism study of poly(4-methyl-1,3-pentadiene) and poly(4-methyl-1-pentene) prepared by using rac-[CH 2 (3- tert -butyl-1-indenyl) 2 ]ZrCl 2 / 13 C enriched methylaluminoxane" @default.
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• W2735048948 doi "https://doi.org/10.1016/j.eurpolymj.2017.07.024" @default.
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