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- W2735078312 abstract "Abstract A rhodium‐Josiphos(L*) catalyzed enantioselective intramolecular hydroarylation reaction is described. The reductive cyclization of o ‐bromoaniline‐derived acrylamides provides convenient access to 3,3‐disubstituted oxindoles in good yields and with excellent enantioselectivity across a range of substrates. We propose that the key cyclization proceeds via a rhodium(III) intermediate. Overall, this method represents an unusual mode of reactivity for rhodium catalysis and is complementary to palladium(0)‐catalyzed α‐arylation methods." @default.
- W2735078312 created "2017-07-21" @default.
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- W2735078312 date "2017-08-14" @default.
- W2735078312 modified "2023-09-30" @default.
- W2735078312 title "Rhodium-Catalyzed Enantioselective Reductive Arylation: Convenient Access to 3,3-Disubstituted Oxindoles" @default.
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- W2735078312 doi "https://doi.org/10.1002/anie.201704922" @default.
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