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• W2735172023 abstract "Transition metal compounds sometimes exhibit beautiful colors. We report here on a new oxychloride Ca3ReO5Cl2 which shows unusually distinct pleochroism; that is, the material exhibits different colors depending on viewing directions. This ple-ochroism is a consequence of the fact that a complex crystal field splitting of the 5d orbitals of the Re6+ ion in a square-pyramidal coordination of low-symmetry occurs accidentally in the energy range of the visible light spectrum. Since the rele-vant d-d transitions possess characteristic polarization dependences according to the optical selection rule, the orbital states are visible in Ca3ReO5Cl2." @default.
• W2735172023 created "2017-07-21" @default.
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• W2735172023 date "2017-07-27" @default.
• W2735172023 modified "2023-10-17" @default.
• W2735172023 title "“Visible” 5d Orbital States in a Pleochroic Oxychloride" @default.
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• W2735172023 doi "https://doi.org/10.1021/jacs.7b05128" @default.
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