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• W2735199967 abstract "Biocatalysis is gaining increasing attention in the academic and industrial sector due to the possibility of developing highly stereoselective transformations in a sustainable manner. The creation of stereogenic centres in organic synthesis is not trivial and multiple approaches have been disclosed based on organometallic and organocatalytic methods with the use of day by day more complex catalysts to induce asymmetry in selected transformations. The intrinsic chirality of enzymes makes them powerful tools for the development of stereoselective transformations, catalysing a wide range of chemical reactions due to the high abundance and diversity of enzymes in nature. In addition, the enormous advances in rational design and molecular biology methods have opened up the possibility to create more robust and versatile biocatalysts, which have improved the initial activities displayed by wild-type enzymes. Therefore, their applicability has been widely increased in terms of reaction conditions, substrate specificity, activity and selectivity among others. All these properties have attracted the industrial sector, which has taken advantage of the enzyme selectivities in multiple scenarios. Herein, the focus has been put in recent developments of stereoselective transformations for the synthesis of valuable building blocks towards the production of pharmaceuticals and biologically active natural products." @default.
• W2735199967 created "2017-07-21" @default.
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• W2735199967 date "2017-07-10" @default.
• W2735199967 modified "2023-10-16" @default.
• W2735199967 title "Stereoselective biocatalysis: A mature technology for the asymmetric synthesis of pharmaceutical building blocks" @default.
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• W2735199967 doi "https://doi.org/10.1080/10242422.2017.1340457" @default.
• W2735199967 hasPublicationYear "2017" @default.
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