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- W2735532364 abstract "A new catalyst system capable of selective chloride functionalization in the Pd-catalyzed amination of 3,2- and 5,2- Br/Cl-pyridines is reported. A reaction optimization strategy employing ligand parametrization led to the identification of 1,1'-bis[bis(dimethylamino)phosphino]ferrocene DMAPF, a readily available yet previously unutilized diphosphine, as a uniquely effective ligand for this transformation." @default.
- W2735532364 created "2017-07-21" @default.
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- W2735532364 date "2017-07-27" @default.
- W2735532364 modified "2023-10-17" @default.
- W2735532364 title "Inverting Conventional Chemoselectivity in Pd-Catalyzed Amine Arylations with Multiply Halogenated Pyridines" @default.
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- W2735532364 doi "https://doi.org/10.1021/jacs.7b05409" @default.
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